全文获取类型
收费全文 | 1092篇 |
免费 | 78篇 |
国内免费 | 42篇 |
专业分类
化学 | 665篇 |
晶体学 | 9篇 |
力学 | 57篇 |
综合类 | 22篇 |
数学 | 136篇 |
物理学 | 323篇 |
出版年
2023年 | 11篇 |
2022年 | 19篇 |
2021年 | 17篇 |
2020年 | 37篇 |
2019年 | 37篇 |
2018年 | 23篇 |
2017年 | 23篇 |
2016年 | 55篇 |
2015年 | 49篇 |
2014年 | 53篇 |
2013年 | 56篇 |
2012年 | 83篇 |
2011年 | 87篇 |
2010年 | 50篇 |
2009年 | 43篇 |
2008年 | 76篇 |
2007年 | 55篇 |
2006年 | 53篇 |
2005年 | 37篇 |
2004年 | 49篇 |
2003年 | 24篇 |
2002年 | 23篇 |
2001年 | 22篇 |
2000年 | 25篇 |
1999年 | 22篇 |
1998年 | 19篇 |
1997年 | 5篇 |
1996年 | 15篇 |
1995年 | 9篇 |
1994年 | 7篇 |
1993年 | 22篇 |
1992年 | 15篇 |
1991年 | 15篇 |
1990年 | 10篇 |
1989年 | 9篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 6篇 |
1985年 | 7篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1980年 | 5篇 |
1979年 | 2篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1966年 | 3篇 |
1936年 | 1篇 |
1863年 | 1篇 |
排序方式: 共有1212条查询结果,搜索用时 15 毫秒
1.
2.
3.
Emily J. Hopkins Dr. Yurii Prots Dr. Ulrich Burkhardt Dr. Yves Watier Dr. Zhiwei Hu Dr. Chang‐Yang Kuo Dr. Jen‐Che Chiang Dr. Tun‐Wen Pi Dr. Arata Tanaka Prof. Liu Hao Tjeng Dr. Martin Valldor 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(21):7938-7943
Through a solid‐state reaction, a practically phase pure powder of Ba3V2S4O3 was obtained. The crystal structure was confirmed by X‐ray single‐crystal and synchrotron X‐ray powder diffraction (P63, a=10.1620(2), c=5.93212(1) Å). X‐ray absorption spectroscopy, in conjunction with multiplet calculations, clearly describes the vanadium in charge‐disproportionated VIIIS6 and VVSO3 coordinations. The compound is shown to be a strongly correlated Mott insulator, which contradicts previous predictions. Magnetic and specific heat measurements suggest dominant antiferromagnetic spin interactions concomitant with a weak residual ferromagnetic component, and that intrinsic geometric frustration prevents long‐range order from evolving. 相似文献
4.
Nonlinear Dynamics - This paper concerns the dissipativity and contractivity of the Caputo fractional initial value problems. We prove that the systems have an absorbing set under the same... 相似文献
5.
Prof. Vladimir I. Bregadze Prof. Igor B. Sivaev Ravindra Dhar Dubey Prof. Andrey Semioshkin Dr. Akim V. Shmal'ko Dr. Irina D. Kosenko Kseniya V. Lebedeva Prof. Swadhin Mandal Prasannakumar Sreejyothi Arindam Sarkar Prof. Zheyu Shen Prof. Aiguo Wu Prof. Narayan S. Hosmane 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(61):13832-13841
A series of boron-containing lipids were prepared by reactions of cyclic oxonium derivatives of polyhedron boranes and metallacarboranes (closo-dodecaborate anion, cobalt and iron bis(dicarbollides)) with amine and carboxylic acids which are derived from cholesterol. Stable liposomal formulations, on the basis of synthesized boron-containing lipids, hydrogenated soybean l -α-phosphatidylcholine and (HSPC) 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-N-[methoxy(polyethylene glycol)-2000] (DSPE-PEG) as excipients, were prepared and then characterized by dynamic light scattering (DLS) that revealed the formation of particles to be smaller than 200 nm in diameter. The resulting liposomal formulations showed moderate to excellent loading and entrapment efficiency, thus justifying the design of the compounds to fit in the lipid bilayer and ensuring ease of in vivo use for future application. The liposomal formulations based on cobalt and iron bis(dicarbollide)-based lipids were found to be nontoxic against both human breast normal epithelial cells MCF-10A and human breast cancer cells MCF-7. 相似文献
6.
Katarina Leko Marko Hanževački Dr. Zlatko Brkljača Dr. Katarina Pičuljan Dr. Rosana Ribić Dr. Josip Požar 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(23):5208-5219
The effects of solvent and temperature on the complexation of adamantyl mannoside with β-cyclodextrin and 6-O-monotosyl-6-deoxy-β-cyclodextrin were explored experimentally and by means of molecular dynamics simulations. Efficient binding was observed only in hydrogen-bonded solvents, which indicated solvophobically driven complexation. The stability of the inclusion complex was considerably higher in aqueous media. A pronounced temperature dependence of ΔrH○ and ΔrS○, resulting in perfect enthalpy–entropy compensation, was observed in water. The complexation thermodynamics was in line with classical rationale for the hydrophobic effect at lower temperatures and the nonclassical explanation at higher temperatures. This finding linked cyclodextrin complexation thermodynamics with insights regarding the effect of temperature on the hydration water structure. The complexation enthalpies and entropies were weakly dependent on temperature in organic media. The signs of ΔrH○ and ΔrS○ were in accordance with the nonclassical hydrophobic (solvophobic) effect. The structures of the optimized product corresponded to those deduced spectroscopically, and the calculated and experimentally obtained values of ΔrG○ were in very good agreement. This investigation clearly demonstrated that solvophobically driven formation of cyclodextrin complexes could be anticipated in structured solvents in general. However, unlike in water, adamantane and the host cavity behaved solely as structure breakers in the organic media explored so far. 相似文献
7.
Dr. Yanwei Cao Wenjing Li Tian Gao Pi Ding Prof. Dr. Renjun Pei 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(39):8631-8638
Numerous studies have shown compelling evidence that incorporation of an inversion of polarity site (IPS) in G-rich sequences can affect the topological and structural characteristics of G-quadruplexes (G4s). Herein, the influence of IPS on the formation of a previously studied intramolecular parallel G4 of d(G3TG3TG3TG3) (TTT) and its stacked higher-order structures is explored. Insertion of 3′–3′ or 5′–5′ IPS did not change the parallel folding pattern of TTT. However, both the species and position of the IPS in TTT have a significant impact on the G4 stability and end-stacking through the alteration of G4–G4 interfaces properties. The data demonstrate that one base flip in each terminal G-tetrad can stabilize parallel G4s and facilitate intermolecular packing of monomeric G4s. Such modifications can also enhance the fluorescence and enzymatic performances by promoting interactions between parallel G4s with N-methyl mesoporphyrin IX (NMM) and hemin, respectively. 相似文献
8.
Journal of Inclusion Phenomena and Macrocyclic Chemistry - Newly phthalocyanine derivative which carries 2,6-dimethoxyphenoxy bioactive groups as tetrakis from non-peripheral positions of the... 相似文献
9.
The nervous system is a significant part of the human body, and peripheral nerve injury caused by trauma can cause various functional disorders. When the broken end defect is large and cannot be repaired by direct suture, small gap sutures of nerve conduits can effectively replace nerve transplantation and avoid the side effect of donor area disorders. There are many choices for nerve conduits, and natural materials and synthetic polymers have their advantages. Among them, the nerve scaffold should meet the requirements of good degradability, biocompatibility, promoting axon growth, supporting axon expansion and regeneration, and higher cell adhesion. Polymer biological scaffolds can change some shortcomings of raw materials by using electrospinning filling technology and surface modification technology to make them more suitable for nerve regeneration. Therefore, polymer scaffolds have a substantial prospect in the field of biomedicine in future. This paper reviews the application of nerve conduits in the field of repairing peripheral nerve injury, and we discuss the latest progress of materials and fabrication techniques of these polymer scaffolds. 相似文献
10.